پیوندهای مفید
آمار
| تعداد نشریات | 21 |
| تعداد شمارهها | 336 |
| تعداد مقالات | 3,500 |
| تعداد مشاهده مقاله | 4,146,016 |
| تعداد دریافت فایل اصل مقاله | 2,901,885 |
Chemically Treated Pistachio Green Hull as an Effective and Economical Adsorbent for Cadmium Removal: Optimization and Mechanistic Insights | ||
| Water Harvesting Research | ||
| دوره 8، شماره 1، 2025، صفحه 30-42 اصل مقاله (976.25 K) | ||
| نوع مقاله: Research Paper | ||
| شناسه دیجیتال (DOI): 10.22077/jwhr.2025.8843.1165 | ||
| نویسندگان | ||
| Fatemeh Deymeh1؛ Ali Ahmadpour* 1؛ Ali Ayati2؛ Mohammad Taghi Hamed Mosavian3؛ Zarrin Es’haghi4 | ||
| 1Department of Chemical Engineering, Faculty of Engineering, Ferdowsi University of Mashhad, Mashhad, Iran/ Industrial Catalysts and Adsorbents and Environment Research Lab., Oil and Gas Research Institute, FUM, Iran. | ||
| 2Department of Chemical Engineering, Faculty of Engineering, Quchan University of Technology, P.O. Box 94771-67335, Quchan, Iran. | ||
| 3Department of Chemical Engineering, Faculty of Engineering, Ferdowsi University of Mashhad, Mashhad, Iran. | ||
| 4Department of Chemistry, Faculty of Science, Payam Noor University of Mashhad, Mashhad, Iran. | ||
| چکیده | ||
| Nowadays, heavy metal contamination in water sources is a critical environmental concern directly related to human health, necessitating the development of sustainable and cost-effective remediation techniques. Traditional adsorbents are often expensive and less environmentally friendly, highlighting the need for alternative materials with high adsorption efficiency. This study proposes using pistachio green hull, an agricultural byproduct, in both untreated and chemically treated forms as an adsorbent for removing cadmium (Cd2+) from aqueous solutions. Batch adsorption experiments were conducted using untreated, HNO3-treated, NH3/H2O2-treated, and acetone/H2O2-treated pistachio green hulls at an initial Cd2+ ions concentration of 20 mg/L. The adsorption kinetics, equilibrium isotherms, and pH dependence were analyzed to determine the adsorption efficiency and mechanism. The removal efficiencies for untreated, HNO3-treated, NH3/H2O2-treated, and acetone/H2O2-treated samples in laboratory scale were 68%, 55%, 88%, and 95%, respectively. Maximum adsorption occurred within a broad pH range of 4-9. The kinetic analysis revealed that Cd2+ adsorption follows a pseudo-second-order model, with rapid adsorption (<4 min). The adsorption isotherm followed the Langmuir model, suggesting monolayer adsorption, and electrostatic interactions were identified as a key mechanism. The findings demonstrate that pistachio green hulls, particularly after chemical modifications, serve as an effective and eco-friendly adsorbent for Cd2+ removal. This study contributes to advancing sustainable and low-cost solutions for heavy metal remediation. | ||
| کلیدواژهها | ||
| Adsorption؛ Cadmium؛ Chemical treatment؛ Isotherm؛ Pistachio green hull | ||
| مراجع | ||
|
Abdolali, A., Ngo, H. H., Guo, W., Lu, S., Chen, S.-S., Nguyen, N. C., Zhang, X., Wang, J. & Wu, Y. (2016). A breakthrough biosorbent in removing heavy metals: Equilibrium, kinetic, thermodynamic and mechanism analyses in a lab-scale study. Science of The Total Environment, 542, 603–611.
Ahmad, I., Akhtar, M. J., Jadoon, I. B. K., Imran, M., Imran, M. & Ali, S. (2017). Equilibrium modeling of cadmium biosorption from aqueous solution by compost. Environmental Science and Pollution Research, 24(6), 5277–5284.
Ahmad, T. & Danish, M. (2018). Prospects of banana waste utilization in wastewater treatment: A review. Journal of Environmental Management, 206, 330–348.
Almasi, A., Omidi, M., Khodadadian, M., Khamutian, R. & Gholivand, M. B. (2012). Lead(II) and cadmium(II) removal from aqueous solution using processed walnut shell: kinetic and equilibrium study. Toxicological & Environmental Chemistry, 94(4), 660–671.
Alsulaili, A., Elsayed, K. & Refaie, A. (2024). Utilization of agriculture waste materials as sustainable adsorbents for heavy metal removal: A comprehensive review. Journal of Engineering Research, 12(4), 691–703.
Armagan, B. & Toprak, F. (2015). Using pistachio shell for Remazol Red removal from aqueous solutions: equilibrium, kinetics and thermodynamics. Desalination and Water Treatment, 56(1), 136–145.
Bhattacharyya, K., Sen, D., Banik, A. K. & Ganguly, S. (2024). Adsorptive removal of cadmium from aqueous medium-a critical review. Physics and Chemistry of the Earth, Parts A/B/C, 134, 103538-103555.
Deniz, F. & Kepekci, R. A. (2016). Dye biosorption onto pistachio by-product: A green environmental engineering approach. Journal of Molecular Liquids, 219, 194–200.
Dorri, H., Zeraatkar Moghaddam, A., Ghiamati, E. & Barikbin, B. (2022). A comprehensive study on the adsorption-photocatalytic processes using CoFe2O4/SiO2/MnO2 magnetic nanocomposite as a novel photo-catalyst for removal of Cr (VI) under simulated sunlight: Isotherm, kinetic and thermodynamic studies. Journal of Environmental Health Science and Engineering, 1–19.
Doshi, B., Ayati, A., Tanhaei, B., Repo, E. & Sillanpää, M. (2018). Partially carboxymethylated and partially cross-linked surface of chitosan versus the adsorptive removal of dyes and divalent metal ions. Carbohydrate Polymers, 197, 586–597.
Dutta, A., Diao, Y., Jain, R., Rene, E. R. & Dutta, S. (2016). Adsorption of Cadmium from Aqueous Solutions onto Coffee Grounds and Wheat Straw: Equilibrium and Kinetic Study. Journal of Environmental Engineering, 142(9), 1–6.
Fiyadh, S. S., Alardhi, S. M., Al Omar, M., Aljumaily, M. M., Al Saadi, M. A., Fayaed, S. S., Ahmed, S. N., Salman, A. D., Abdalsalm, A. H., Jabbar, N. M. & El-Shafi, A. (2023). A comprehensive review on modelling the adsorption process for heavy metal removal from waste water using artificial neural network technique. Heliyon, 9(4), e15455–e15468.
Foo, K. Y. & Hameed, B. H. (2011). Preparation and characterization of activated carbon from pistachio nut shells via microwave-induced chemical activation. Biomass and Bioenergy, 35(7), 3257–3261.
Gogoi, B., Acharjee, S. A., Bharali, P., Sorhie, V., Walling, B. & Alemtoshi. (2024). A critical review on the ecotoxicity of heavy metal on multispecies in global context: A bibliometric analysis. Environmental Research, 248, 118280–118304.
Gupta, V. K. & Nayak, A. (2012). Cadmium removal and recovery from aqueous solutions by novel adsorbents prepared from orange peel and Fe2O3 nanoparticles. Chemical Engineering Journal, 180, 81–90.
Hamdaoui, O. (2009). Removal of cadmium from aqueous medium under ultrasound assistance using olive leaves as sorbent. Chemical Engineering and Processing: Process Intensification, 48(6), 1157–1166.
Horsfall, M. & Spiff, A. I. (2005). Effects of temperature on the sorption of Pb2+ and Cd 2+ from aqueous solution by Caladium bicolor (Wild Cocoyam) biomass. Electronic Journal of Biotechnology, 8(2), 162–169.
Jamkar, S., Tripathy, A., Mallik, S. & Pal, D. (2023). Methodologies of Removal of Heavy Metals from Contaminated Water Using Various Waste Materials: A Comprehensive Review. ChemBioEng Reviews, 10(6), 959–992.
Joshi, H. K., Vishwakarma, M. C., Kumar, R., Sharma, H., Bhandari, N. S. & Joshi, S. K. (2023). The biosorption of Zn2+ by various biomasses from wastewater: A review. Journal of Water Process Engineering, 56, 104389–104414.
Karić, N., Maia, A. S., Teodorović, A., Atanasova, N., Langergraber, G., Crini, G., Ribeiro, A. R. L. & Đolić, M. (2022). Bio-waste valorisation: Agricultural wastes as biosorbents for removal of (in)organic pollutants in wastewater treatment. Chemical Engineering Journal Advances, 9, 100239–100256.
Karimi, F., Ayati, A., Tanhaei, B., Sanati, A. L., Afshar, S., Kardan, A., Dabirifar, Z. & Karaman, C. (2022). Removal of metal ions using a new magnetic chitosan nano-bio-adsorbent; A powerful approach in water treatment. Environmental Research, 203, 111753–111761.
Khan, M. A., Al Othman, Z. A., Kumar, M., Ola, M. S. & Siddique, M. R. (2015). Biosorption potential assessment of modified pistachio shell waste for methylene blue: thermodynamics and kinetics study. Desalination and Water Treatment, 56(1), 146–160.
Najafi, M., Bastami, T. R., Binesh, N., Ayati, A. & Emamverdi, S. (2022). Sono-sorption versus adsorption for the removal of congo red from aqueous solution using NiFeLDH/Au nanocomposite: Kinetics, thermodynamics, isotherm studies, and optimization of process parameters. Journal of Industrial and Engineering Chemistry, 116, 489–503.
Nguyen, T. A. H., Ngo, H. H., Guo, W. S., Zhang, J., Liang, S., Yue, Q. Y., Li, Q. & Nguyen, T. V. (2013). Applicability of agricultural waste and by-products for adsorptive removal of heavy metals from wastewater. Bioresource Technology, 148, 574–585.
Osman, A. I., Ayati, A., Farghali, M., Krivoshapkin, P., Tanhaei, B., Karimi-Maleh, H., Krivoshapkina, E., Taheri, P., Tracey, C., Al-Fatesh, A., Ihara, I., Rooney, D. W. & Sillanpaä, M. (2024). Advanced adsorbents for ibuprofen removal from aquatic environments: a review. Environmental Chemistry Letters, 22(1), 373–418.
Oxley, J. C., Brady, J., Wilson, S. A. & Smith, J. L. (2012). The risk of mixing dilute hydrogen peroxide and acetone solutions. Journal of Chemical Health and Safety, 19(2), 27–33.
Rahman, D. Z., Vijayaraghavan, J. & Thivya, J. (2023). A comprehensive review on zinc(II) sequestration from wastewater using various natural/modified low-cost agro-waste sorbents. Biomass Conversion and Biorefinery, 13(7), 5469–5499.
Ramesh, B., Saravanan, A., Senthil Kumar, P., Yaashikaa, P. R., Thamarai, P., Shaji, A. & Rangasamy, G. (2023). A review on algae biosorption for the removal of hazardous pollutants from wastewater: Limiting factors, prospects and recommendations. Environmental Pollution, 327, 121572–121585.
Sadeghi, S., Rad, F. A. & Moghaddam, A. Z. (2014). A highly selective sorbent for removal of Cr(VI) from aqueous solutions based on Fe3O4/poly(methyl methacrylate) grafted Tragacanth gum nanocomposite: Optimization by experimental design. Materials Science and Engineering C, 45, 136–145.
Santhosh, K., Kamala, K., Ramasamy, P., Musthafa, M. S., Almujri, S. S., Asdaq, S. M. B. & Sivaperumal, P. (2024). Unveiling the silent threat: Heavy metal toxicity devastating impact on aquatic organisms and DNA damage. Marine Pollution Bulletin, 200, 116139–116148.
Sarangi, B. & Mishra, S. P. (2023). A glance at the potential of Artocarpus genus fruit peels and its derivatives as adsorbent. Bioresource Technology Reports, 21, 101363–101374.
Saravanan, A., Karishma, S., Kumar, P. S., Thamarai, P. & Yaashikaa, P. R. (2023). Recent insights into mechanism of modified bio-adsorbents for the remediation of environmental pollutants. Environmental Pollution, 339, 122720–122738.
Solangi, N. H., Kumar, J., Mazari, S. A., Ahmed, S., Fatima, N. & Mubarak, N. M. (2021). Development of fruit waste derived bio-adsorbents for wastewater treatment: A review. Journal of Hazardous Materials, 416, 125848–125879.
Sudrajat, H., Susanti, A., Putri, D. K. Y. & Hartuti, S. (2021). Mechanistic insights into the adsorption of methylene blue by particulate durian peel waste in water. Water Science and Technology, 84(7), 1774–1792.
Tanhaei, B., Ayati, A., Lahtinen, M. & Sillanpää, M. (2015). Preparation and characterization of a novel chitosan/Al2O3/magnetite nanoparticles composite adsorbent for kinetic, thermodynamic and isotherm studies of Methyl Orange adsorption. Chemical Engineering Journal, 259, 1–10.
Tanhaei, B., Ayati, A. & Sillanpää, M. (2019). Magnetic xanthate modified chitosan as an emerging adsorbent for cationic azo dyes removal: Kinetic, thermodynamic and isothermal studies. International Journal of Biological Macromolecules, 121, 1126–1134.
Teğin, İ., Öc, S. & Saka, C. (2025). Adsorption of copper (II) from aqueous solutions using adsorbent obtained with sodium hydroxide activation of biochar prepared by microwave pyrolysis. Biomass Conversion and Biorefinery, 15, 6805–6816.
Wan Ngah, W. S. & Hanafiah, M. A. K. M. (2008). Removal of heavy metal ions from wastewater by chemically modified plant wastes as adsorbents: A review. Bioresource Technology, 99(10), 3935–3948.
Xue, X., Han, Y., Wu, X., Wang, H., Wang, S., Zheng, J., Ran, R. & Zhang, C. (2023). Review: Phytate modification serves as a novel adsorption strategy for the removal of heavy metal pollution in aqueous environments. Journal of Environmental Chemical Engineering, 11(6), 111440–111465.
Yeow, P. K., Wong, S. W. & Hadibarata, T. (2021). Removal of azo and anthraquinone dye by plant biomass as adsorbent – a review. Biointerface Research in Applied Chemistry, 11(1), 8218–8232.
Zeraatkar Moghaddam, A., Esmaeilkhanian, E. & Shakourian-Fard, M. (2019). Immobilizing magnetic glutaraldehyde cross-linked chitosan on graphene oxide and nitrogen-doped graphene oxide as well-dispersible adsorbents for chromate removal from aqueous solutions. International Journal of Biological Macromolecules, 128, 61–73. | ||
|
آمار تعداد مشاهده مقاله: 314 تعداد دریافت فایل اصل مقاله: 276 |
||
نماد الکترونیک
سامانه مدیریت نشریات علمی. قدرت گرفته از سیناوب